Some examples of recent advances in experiment and theory that have impact on solution of the glass transition problem are briefly discussed. The fundamental importance of a special class of secondary relaxations called the Johari-Goldstein beta-relaxations becomes clear from the recent advances. The main part of the paper addresses a recent research problem, which is the purported anomalous temperature dependence of the relaxation time of another secondary (gamma) relaxation found by fitting dielectric relaxation data in several glass-formers. We show the anomalous T-dependence of this faster gamma-relaxation is caused by the influence exerted by the slower Johari-Goldstein beta-relaxation in the vicinity. (C) 2008 Elsevier B.V. All rights reserved.

Recent advances in fundamental understanding of glass transition

CAPACCIOLI, SIMONE
2008-01-01

Abstract

Some examples of recent advances in experiment and theory that have impact on solution of the glass transition problem are briefly discussed. The fundamental importance of a special class of secondary relaxations called the Johari-Goldstein beta-relaxations becomes clear from the recent advances. The main part of the paper addresses a recent research problem, which is the purported anomalous temperature dependence of the relaxation time of another secondary (gamma) relaxation found by fitting dielectric relaxation data in several glass-formers. We show the anomalous T-dependence of this faster gamma-relaxation is caused by the influence exerted by the slower Johari-Goldstein beta-relaxation in the vicinity. (C) 2008 Elsevier B.V. All rights reserved.
2008
Ngai, K. L.; Grzybowska, K.; Grzybowski, A.; Kaminska, E.; Kaminski, K.; Paluch, M.; Capaccioli, Simone
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11568/125550
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