By using a V-V- or Mo-VI-catalyzed two-phase procedure for oxybromination of organic substrates, adamantylideneadamantane bromonium salts (ADABr(+)X(-); X- = V-V- and Mo-VI-containing anions) have been isolated and characterized. These salts proved to be significantly more stable relative to the corresponding tribromide derivative.
Direct synthesis of stable adamantylideneadamantane bromonium salts
CHIAPPE, CINZIA;
1999-01-01
Abstract
By using a V-V- or Mo-VI-catalyzed two-phase procedure for oxybromination of organic substrates, adamantylideneadamantane bromonium salts (ADABr(+)X(-); X- = V-V- and Mo-VI-containing anions) have been isolated and characterized. These salts proved to be significantly more stable relative to the corresponding tribromide derivative.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.