The diamine N <^> N (N <^> N = 6-(2-dimethylaminoethyl)-6,7-dihydro-5-H-dibenz[c,e]azepin (1)) has been prepared and characterised. It reacts with nickel(II) chloride and bis(benzonitrile)dichloropalladium giving the corresponding complexes MCl2(N <^> N) (M = Ni, 6; Pd, 7) whose crystal structures have been determined. The nickel coordination in complex 6 is distorted tetrahedral, whereas the palladium coordination in complex 7 is square planar. (C) 1999 Elsevier Science S.A. All rights reserved.
Synthesis and X-ray crystallographic structures of dichloronickel(II) and -palladium(II) complexes containing the biphenyl diamine ligand 6-(2-dimethylaminoethyl)-6,7-dihydro-5-H-dibenz[c,e]azepin
MARCHETTI, FABIO;
1999-01-01
Abstract
The diamine N <^> N (N <^> N = 6-(2-dimethylaminoethyl)-6,7-dihydro-5-H-dibenz[c,e]azepin (1)) has been prepared and characterised. It reacts with nickel(II) chloride and bis(benzonitrile)dichloropalladium giving the corresponding complexes MCl2(N <^> N) (M = Ni, 6; Pd, 7) whose crystal structures have been determined. The nickel coordination in complex 6 is distorted tetrahedral, whereas the palladium coordination in complex 7 is square planar. (C) 1999 Elsevier Science S.A. All rights reserved.File in questo prodotto:
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