The title reaction gives allylic hydroxylation and epoxidation products in about 2:1 ratio, 1-methyl-1,2-epoxycyclohexane being formed with a 46% e.e. of the (1R,2S) enantiomer.
THE CYTOCHROME-P-450 CATALYZED OXIDATION OF 1-METHYLCYCLOHEXENE - COMPETITION BETWEEN HYDROXYLATION AND EPOXIDATION AND ABSOLUTE STEREOCHEMISTRY OF THE EPOXIDATION
CHIAPPE, CINZIA;
1991-01-01
Abstract
The title reaction gives allylic hydroxylation and epoxidation products in about 2:1 ratio, 1-methyl-1,2-epoxycyclohexane being formed with a 46% e.e. of the (1R,2S) enantiomer.File in questo prodotto:
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