Cross-sections, photoelectron angular distribution parameters and branching ratios for the ionization of the outer-valence 5a(1), 2e and inner-valence 4a(1) shells of phosphine have been calculated up to a photon energy of 90 eV. Ab-initio calculations have been performed, by the K-matrix technique and projection on basis sets of L-2 functions, in the random phase approximation for the three coupled ionization channels. The theoretical results, compared with the available experimental data and with recent semi-empirical calculations, show a quantitative agreement with the experiment. (C) 1999 Elsevier Science B.V. All rights reserved.

Calculation of the differential photoionization cross-section of PH3

CACELLI, IVO
1999-01-01

Abstract

Cross-sections, photoelectron angular distribution parameters and branching ratios for the ionization of the outer-valence 5a(1), 2e and inner-valence 4a(1) shells of phosphine have been calculated up to a photon energy of 90 eV. Ab-initio calculations have been performed, by the K-matrix technique and projection on basis sets of L-2 functions, in the random phase approximation for the three coupled ionization channels. The theoretical results, compared with the available experimental data and with recent semi-empirical calculations, show a quantitative agreement with the experiment. (C) 1999 Elsevier Science B.V. All rights reserved.
1999
Carravetta, V; Cacelli, Ivo
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11568/164865
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