The complexes [PtCl3(C2H4)]-[AmH]+ and trans- [PtCl2(Am)(C2H4)], containing the binaphthyl secondary amine (S)-3,5-dihydro-4H-dinaphth[2,1-c:19,29-e]azepine,are efficient and versatile CDAs for the enantiodicrimination of simple olefins by 195Pt NMR analysis of their diastereoisomeric derivatives
trans-PtCl2(Am)(C2H4) and [PtCl3(C2H4)]-[AmH]+ containing a binaphthyl secondary amine: efficient Chiral Derivatizing Agents for the enantiodiscrimination of chiral olefins by 195Pt NMR spectroscopy
UCCELLO BARRETTA, GLORIA;BALZANO, FEDERICA;CAPORUSSO, ANNA MARIA;SALVADORI, PIERO
2001-01-01
Abstract
The complexes [PtCl3(C2H4)]-[AmH]+ and trans- [PtCl2(Am)(C2H4)], containing the binaphthyl secondary amine (S)-3,5-dihydro-4H-dinaphth[2,1-c:19,29-e]azepine,are efficient and versatile CDAs for the enantiodicrimination of simple olefins by 195Pt NMR analysis of their diastereoisomeric derivativesFile in questo prodotto:
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