Carboxylato-bridged Ru(l) carbonyl complexes are activated by CO towards both disproportionation and reaction with dihydrogen, through the intermediacy of the unbridged metal-metal bonded valence isomers (OC)5RuRu(CO)3(OCOCR3)2 and [Ru(CO)4(OCOCR3)]2.
Reactive Intermediates from Carbonylation of Ruthenium(I) Carbonyl Carboxylates. Isolation, Molecular Structures and Chemical Properties of Dinuclear Unbridged Ruthenium Carbonyl Trifluoroacetates
FUNAIOLI, TIZIANA;MARCHETTI, FABIO;FACHINETTI, GIUSEPPE
1999-01-01
Abstract
Carboxylato-bridged Ru(l) carbonyl complexes are activated by CO towards both disproportionation and reaction with dihydrogen, through the intermediacy of the unbridged metal-metal bonded valence isomers (OC)5RuRu(CO)3(OCOCR3)2 and [Ru(CO)4(OCOCR3)]2.File in questo prodotto:
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