The niobium(0) compound [Nb(mes)2] (mes = 1,3,5-trimethylbenzene) was prepared not only by metal atom - ligand cocondensation, but also according to Equation (a). The chemical behavior of this compound is similar to that of the analogous complex [V(mes)2]. For example, it reacts under carbon monoxide atmosphere to give the green salt [Nb(mes)2(CO)] [Nb(CO)6]. This new, simple approach to niobium(0) compounds should facilitate their study (DME = dimethoxyethane).

THE REDUCTION OF THE NBX5/AIX3 SYSTEM WITH ALUMINUM IN THE PRESENCE OF AROMATIC-HYDROCARBONS - AN APPROACH TO NIOBIUM(II), NIOBIUM(I), AND NIOBIUM(0) ORGANOMETALLICS

CALDERAZZO, FAUSTO;PAMPALONI, GUIDO;
1991-01-01

Abstract

The niobium(0) compound [Nb(mes)2] (mes = 1,3,5-trimethylbenzene) was prepared not only by metal atom - ligand cocondensation, but also according to Equation (a). The chemical behavior of this compound is similar to that of the analogous complex [V(mes)2]. For example, it reacts under carbon monoxide atmosphere to give the green salt [Nb(mes)2(CO)] [Nb(CO)6]. This new, simple approach to niobium(0) compounds should facilitate their study (DME = dimethoxyethane).
1991
Calderazzo, Fausto; Pampaloni, Guido; Rocchi, L; Straehle, J; Wurst, K.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11568/19463
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