The ionic complex [PtCl3(C2H4)]-[(S,S)-(PhMeCH)2NH2]+ containing a chiral secondary amine is a new and versatile chiral derivatizing agent (CDA) for the determination of the enantiomeric composition of several unsaturated compounds including simple olefins: the diastereoisomeric mixtures arising from the exchange of ethylene by the unsaturated analytes are easily detected by 195Pt NMR spectroscopy.

[PtCl3(C2H4)]-[(S,S)-(PhMeCH)2NH2]+: A new and versatile ionic organometallic chiral derivatizing agent for the determination of the enantiomeric composition of chiral unsaturated compounds by 195Pt NMR spectroscopy

UCCELLO BARRETTA, GLORIA;LAZZARONI, RAFFAELLO;SALVADORI, PIERO
2000-01-01

Abstract

The ionic complex [PtCl3(C2H4)]-[(S,S)-(PhMeCH)2NH2]+ containing a chiral secondary amine is a new and versatile chiral derivatizing agent (CDA) for the determination of the enantiomeric composition of several unsaturated compounds including simple olefins: the diastereoisomeric mixtures arising from the exchange of ethylene by the unsaturated analytes are easily detected by 195Pt NMR spectroscopy.
2000
UCCELLO BARRETTA, Gloria; Bernardini, R.; Lazzaroni, Raffaello; Salvadori, Piero
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11568/200214
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