The reaction of TiCl4 with SeOCl2 affords the mu-oxo derivative [TiCl3(SeOCl2)(2)](2)(mu-O) through a deoxygenation reaction of SeOCl2 to SeCl4 whereas ZrCl4 gives 1:1 or 1:2 adducts of formula ZrCl4(SeOCl2)(n), n=1, 2.
Reactivity of SeOCl2 with titanium and zirconium tetrachlorides. The unexpected formation of a µ-oxo-bridged titanium(IV) derivative
CALDERAZZO, FAUSTO;MARCHETTI, FABIO;PAMPALONI, GUIDO
2000-01-01
Abstract
The reaction of TiCl4 with SeOCl2 affords the mu-oxo derivative [TiCl3(SeOCl2)(2)](2)(mu-O) through a deoxygenation reaction of SeOCl2 to SeCl4 whereas ZrCl4 gives 1:1 or 1:2 adducts of formula ZrCl4(SeOCl2)(n), n=1, 2.File in questo prodotto:
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