A series of ethers has been prepared whose structures are related to tetrahydropyranyl and tetrahydrofuranyl derivatives with floral odors by replacement of either one of the two oxygen atoms with a methylene group. 2-Substituted tetrahydropyrans and tetrahydrofurans, as well as cyclohexyl and cyclopentyl ethers, have thus been obtained by substitution of the exocyclic or the endocyclic oxygen, respectively. None of the compounds exhibited a pure floral odor, although in several of them this note was present as a secondary character. The data contribute to a better understanding between structure and floral odor.
SYNTHESIS OF ETHERS RELATED TO SOME FLORAL ODORANTS - EFFECT OF OXYGEN/CARBON REPLACEMENT
PELOSI, PAOLO
1994-01-01
Abstract
A series of ethers has been prepared whose structures are related to tetrahydropyranyl and tetrahydrofuranyl derivatives with floral odors by replacement of either one of the two oxygen atoms with a methylene group. 2-Substituted tetrahydropyrans and tetrahydrofurans, as well as cyclohexyl and cyclopentyl ethers, have thus been obtained by substitution of the exocyclic or the endocyclic oxygen, respectively. None of the compounds exhibited a pure floral odor, although in several of them this note was present as a secondary character. The data contribute to a better understanding between structure and floral odor.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
