Some new hexacarbonylniobate(-I) derivatives have been prepared; the bis( triphenylphosphine)iminium derivative, which has been shown by X-ray diffraction methods to be isostructural with the corresponding hexacarbonylvanadate(- I) compound, contains essentially linear and octahedral [(PPh,),N]+ and [Nb (CO),]- ions, respectively
THE HEXACARBONYLNIOBATE(-I) ANION
CALDERAZZO, FAUSTO;PAMPALONI, GUIDO;
1982-01-01
Abstract
Some new hexacarbonylniobate(-I) derivatives have been prepared; the bis( triphenylphosphine)iminium derivative, which has been shown by X-ray diffraction methods to be isostructural with the corresponding hexacarbonylvanadate(- I) compound, contains essentially linear and octahedral [(PPh,),N]+ and [Nb (CO),]- ions, respectivelyFile in questo prodotto:
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