A circular dichroic (CD) exciton chirality method based on host-guest chiral recognition has been developed to determine the absolute configuration of carboxylic acids with an α-stereogenic center; an amide C=O->Zn coordination, identified by infrared spectroscopy and computations, is involved in this complexation.
Configurational Assignment of a-Chiral Carboxylic Acids by Complexation to Dimeric Zn-Porphyrin: Host/Guest Structure, Chiral Recognition and Circular Dichroism
PESCITELLI, GENNARO;
2002-01-01
Abstract
A circular dichroic (CD) exciton chirality method based on host-guest chiral recognition has been developed to determine the absolute configuration of carboxylic acids with an α-stereogenic center; an amide C=O->Zn coordination, identified by infrared spectroscopy and computations, is involved in this complexation.File in questo prodotto:
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