A circular dichroic (CD) exciton chirality method based on host-guest chiral recognition has been developed to determine the absolute configuration of carboxylic acids with an α-stereogenic center; an amide C=O->Zn coordination, identified by infrared spectroscopy and computations, is involved in this complexation.

Configurational Assignment of a-Chiral Carboxylic Acids by Complexation to Dimeric Zn-Porphyrin: Host/Guest Structure, Chiral Recognition and Circular Dichroism

PESCITELLI, GENNARO;
2002-01-01

Abstract

A circular dichroic (CD) exciton chirality method based on host-guest chiral recognition has been developed to determine the absolute configuration of carboxylic acids with an α-stereogenic center; an amide C=O->Zn coordination, identified by infrared spectroscopy and computations, is involved in this complexation.
2002
Proni, G; Pescitelli, Gennaro; Huang, X; Quraishi, Nq; Nakanishi, K; Berova, N.
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11568/73949
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 72
  • ???jsp.display-item.citation.isi??? 74
social impact