An Integrated Approach to Design Fluoro Substituted “Smart” Polymers for Protection of Monumental Buildings

Introduction of fluorinated groups in the structure of either fully acrylic or acrylic - vinyl ether copolymers, is achieved through the use of commercially available or specifically synthesized fluorinated acrylic comonomers. If suitably selected, these fluoroacrylates can allow both control on the macromolecular structure and tailoring of material properties that are relevant for coating applications, such as film-forming behavior, adhesion, water repellency and intrinsic photostability. Several copolymers of fluorinated acrylates and methacrylates with not-fluorinated methacrylates and vinyl ethers have been evaluated in terms of chemical stability under accelerated photoaging conditions, and their behavior as protective coating materials has been studied after application to various stone substrates that are commonly found in ancient buildings and objects of cultural significance.