| Nome |
# |
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Revisitation of the PCl5-chlorination reaction of a-amino acids: Spectroscopic and DFT insights, and synthesis of the L-proline-derived 2,5-diketopiperazine, file e0d6c927-c400-fcf8-e053-d805fe0aa794
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1.840
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|
The chemistry of high valent tungsten chlorides with N-substituted ureas, including urea self-protonation reactions triggered by WCl6, file e0d6c927-be1f-fcf8-e053-d805fe0aa794
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612
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|
Synthesis of a highly reactive form of WO2Cl2, its conversion into nanocrystalline mono-hydrated WO3 and coordination compounds with tetramethylurea, file e0d6c927-be20-fcf8-e053-d805fe0aa794
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439
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|
Structural Characterization of a Fluorido-Amide of Niobium, and Facile CO2 Incorporation Affording a Fluorido-Carbamate, file e0d6c92a-9fe9-fcf8-e053-d805fe0aa794
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393
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|
19F NMR spectroscopy as useful tool for determining the structure in solution of coordination compounds of MF5 (M = Nb, Ta), file e0d6c927-c02d-fcf8-e053-d805fe0aa794
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392
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|
The versatile chemistry of niobium pentachloride with aliphatic amines: Aminolysis, metal reduction and C–H activation, file e0d6c927-be72-fcf8-e053-d805fe0aa794
|
369
|
|
Room-temperature polymerization of beta-pinene by niobium and tantalum halides, file e0d6c927-c698-fcf8-e053-d805fe0aa794
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355
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|
A Crystallographic and Spectroscopic Study of the Reactions of WCl6 with Carbonyl Compounds, file e0d6c927-c089-fcf8-e053-d805fe0aa794
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344
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|
The reactivity of MoCl5 with molecules containing the alcohol functionality, file e0d6c927-be84-fcf8-e053-d805fe0aa794
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343
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|
Ligand-interchange reactions between M(iv) (M = Ti, V) oxide bis-acetylacetonates and halides of high-valent group 4 and 5 metals. A synthetic and electrochemical study, file e0d6c927-bea4-fcf8-e053-d805fe0aa794
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290
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|
Molybdenum(V) and Molybdenum(IV) coordination compounds from the reaction of MoCl5 with sulfones, file e0d6c926-9090-fcf8-e053-d805fe0aa794
|
285
|
|
Halo-complexes of Titanium(III): the Thermochromic Behaviour of [NBu4][TiCl4(thf)2], file e0d6c927-c024-fcf8-e053-d805fe0aa794
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279
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|
Epoxide Ring Opening and Insertion into the M–X Bond of Niobium and Tantalum Pentahalides: Synthesis of Dihalide-tris(2-haloalcoholato) Complexes, file e0d6c927-c78f-fcf8-e053-d805fe0aa794
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276
|
|
Different outcomes in the reactions of WCl6 with carboxylic acids, file e0d6c927-bdfc-fcf8-e053-d805fe0aa794
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271
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|
Coordination complexes of niobium and tantalum pentahalides with a bulky NHC ligand, file e0d6c927-c1a4-fcf8-e053-d805fe0aa794
|
268
|
|
A crystallographic and DFT study on a NHC complex of niobium oxide trifluoride, file e0d6c927-c133-fcf8-e053-d805fe0aa794
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254
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|
Stereochemistry of the insertion of disubstituted alkynes into the metal aminocarbyne bond in diiron complexes, file e0d6c927-c2d7-fcf8-e053-d805fe0aa794
|
245
|
|
null, file e0d6c927-c405-fcf8-e053-d805fe0aa794
|
244
|
|
The chemistry of Niobium and Tantalum halides, MX5, with haloacetic acids and their related anhydrides: anhydride C–H bond activation promoted by MF5, file e0d6c927-c106-fcf8-e053-d805fe0aa794
|
240
|
|
null, file e0d6c931-920f-fcf8-e053-d805fe0aa794
|
230
|
|
A general strategy to add diversity to ruthenium arene complexes with bioactive organic compounds: Via a coordinated (4-hydroxyphenyl)diphenylphosphine ligand, file e0d6c929-c7f0-fcf8-e053-d805fe0aa794
|
227
|
|
One pot conversion of benzophenone imine into the relevant 2-aza-allenium, file e0d6c929-dbd3-fcf8-e053-d805fe0aa794
|
226
|
|
C-C bond formation by cyanide addition to dinuclear vinyliminium complexes, file e0d6c927-c28b-fcf8-e053-d805fe0aa794
|
218
|
|
null, file e0d6c927-ad0d-fcf8-e053-d805fe0aa794
|
217
|
|
Further Insights into the Chemistry of Niobium and Tantalum Pentahalides with 1,2-Dialkoxyalkanes: Synthesis of Bromo- and Iodoalkoxides, Spectroscopic and Computational Studies, file e0d6c927-bfb3-fcf8-e053-d805fe0aa794
|
217
|
|
Ruthenium arene complexes with triphenylphosphane ligands: Cytotoxicity towards pancreatic cancer cells, interaction with model proteins, and effect of ethacrynic acid substitution, file e0d6c929-c878-fcf8-e053-d805fe0aa794
|
215
|
|
Modifying bis(triflimide) ionic liquids by dissolving early transition metal carbamates, file e0d6c92a-157b-fcf8-e053-d805fe0aa794
|
213
|
|
Coordination Compounds of Niobium(IV) Oxide Dihalides Including the Synthesis and the Crystallographic Characterization of NHC Complexes, file e0d6c927-c770-fcf8-e053-d805fe0aa794
|
211
|
|
One pot conversion of acetyl chloride to dehydroacetic acid and its coordination in a ruthenium(II) arene complex, file e0d6c929-a717-fcf8-e053-d805fe0aa794
|
205
|
|
Synthesis, characterization and behavior in water/DMSO solution of Ru(II) arene complexes with bioactive carboxylates, file e0d6c92b-3f1c-fcf8-e053-d805fe0aa794
|
204
|
|
Diiron and diruthenium aminocarbyne complexes containing pseudohalides: stereochemistry and reactivity, file e0d6c927-bee6-fcf8-e053-d805fe0aa794
|
203
|
|
null, file e0d6c929-dd4f-fcf8-e053-d805fe0aa794
|
203
|
|
null, file e0d6c927-bfa3-fcf8-e053-d805fe0aa794
|
201
|
|
Addition of alkynes at bridging vinyliminium ligands in diiron complexes: Unprecedented diene formation by enyne-like metathesis, file e0d6c927-bfac-fcf8-e053-d805fe0aa794
|
201
|
|
Reactions of TaF5 with Activated Arenes. Synthesis of [4-(OH)-3-(OCH3)C6H3CH(=O-H)][4-(OH)-3-(OCH3)C6H3CHO][TaF6], a Rare Example of Protonated Aldehyde, file e0d6c927-c5a1-fcf8-e053-d805fe0aa794
|
200
|
|
Vanadium(v) oxoanions in basic water solution: A simple oxidative system for the one pot selective conversion of l-proline to pyrroline-2-carboxylate, file e0d6c92a-0c6d-fcf8-e053-d805fe0aa794
|
195
|
|
SPh functionalized bridging-vinyliminium diiron and diruthenium complexes, file e0d6c927-c183-fcf8-e053-d805fe0aa794
|
193
|
|
Regioselective Nucleophilic Additions to Diiron Carbonyl Complexes Containing a Bridging Aminocarbyne Ligand: A Synthetic, Crystallographic and DFT Study, file e0d6c92a-8963-fcf8-e053-d805fe0aa794
|
192
|
|
Characterization and Thermal Activation of Adducts of Group 4 Tetrahalides with 1,2-Dialkoxyalkanes, file e0d6c927-c030-fcf8-e053-d805fe0aa794
|
189
|
|
Nitrile ligands activation in dinuclear aminocarbyne complexes, file e0d6c927-c26b-fcf8-e053-d805fe0aa794
|
189
|
|
Iron(III) N,N-Dialkylcarbamate-Catalyzed Formation of Cyclic Carbonates from CO2 and Epoxides under Ambient Conditions by Dynamic CO2 Trapping as Carbamato Ligands, file e0d6c930-de26-fcf8-e053-d805fe0aa794
|
184
|
|
Electron exchange reactions between tungsten hexachloride and nitrogen donors, file e0d6c927-bdf8-fcf8-e053-d805fe0aa794
|
180
|
|
Dioxomolybdenum(VI) compounds with α-amino acid donor ligands as catalytic precursors for the selective oxyfunctionalization of olefins, file e0d6c92a-8b42-fcf8-e053-d805fe0aa794
|
176
|
|
Hydride addition at m-vinyliminium ligand obtained from disubstituted alkynes, file e0d6c927-bee8-fcf8-e053-d805fe0aa794
|
174
|
|
New bridging ligands from methylation reactions of m-vinyliminium diiron complexes, file e0d6c927-c294-fcf8-e053-d805fe0aa794
|
171
|
|
Unusual activation pathways of amines in the reactions with molybdenum pentachloride, file e0d6c929-dbd4-fcf8-e053-d805fe0aa794
|
170
|
|
Anticancer Potential of Diiron Vinyliminium Complexes, file e0d6c92e-b944-fcf8-e053-d805fe0aa794
|
170
|
|
C-C bond formation through olefin-thiocarbyne coupling in diiron complexes, file e0d6c927-c190-fcf8-e053-d805fe0aa794
|
168
|
|
Synthesis and Antiproliferative Activity of New Ruthenium Complexes with Ethacrynic-Acid-Modified Pyridine and Triphenylphosphine Ligands, file e0d6c927-be00-fcf8-e053-d805fe0aa794
|
162
|
|
Addition of protic nucleophiles to alkynyl methoxy carbene ligands in diiron complexes, file e0d6c927-c265-fcf8-e053-d805fe0aa794
|
161
|
|
Allowing the direct interaction of: N -aryl α-diimines with a high valent metal chloride: One-pot WCl6-promoted formation of quinoxalinium salts, file e0d6c929-98bd-fcf8-e053-d805fe0aa794
|
160
|
|
Oxido- and Sulfidoniobium(V) N,N-Diethylcarbamates: Synthesis, Characterization and DFT Study, file e0d6c927-bea9-fcf8-e053-d805fe0aa794
|
159
|
|
The reactivity of niobium and tantalum pentahalides with imines, file e0d6c927-c672-fcf8-e053-d805fe0aa794
|
157
|
|
Synthesis, variable temperature NMR investigations and solid state characterisation of novel octafluorofluorene compounds, file e0d6c927-c0a9-fcf8-e053-d805fe0aa794
|
150
|
|
Synthesis and reactivity with amines of new diiron alkynyl methoxy carbene complexes, file e0d6c927-c27b-fcf8-e053-d805fe0aa794
|
145
|
|
Oxidative desulfurization of benzothiophene derivatives with cis-dioxomolybdenum(VI) catalyst precursors, under extractive conditions, file e0d6c92e-6f4d-fcf8-e053-d805fe0aa794
|
144
|
|
Piano Stool Aminoalkylidene-Ferracyclopentenone Complexes from Bimetallic Precursors: Synthesis and Cytotoxicity Data, file e0d6c92e-6772-fcf8-e053-d805fe0aa794
|
143
|
|
Synthesis and Structural Characterization of Non-Homoleptic Carbamato Complexes of V(V) and W(VI) and Their Facile Implantation onto Silica Surfaces, file e0d6c92a-a543-fcf8-e053-d805fe0aa794
|
140
|
|
Synthesis and spectroscopic/DFT structural characterization of coordination compounds of Nb(V) and Ti(IV) with bioactive carboxylic acids, file e0d6c92a-a2cf-fcf8-e053-d805fe0aa794
|
139
|
|
Reactions of diiron MU-aminocarbyne complexes containing nitrile ligands, file e0d6c927-c2db-fcf8-e053-d805fe0aa794
|
133
|
|
Diiron Complexes with a Bridging Functionalized Allylidene Ligand: Synthesis, Structural Aspects, and Cytotoxicity, file e0d6c92f-224b-fcf8-e053-d805fe0aa794
|
129
|
|
Ruthenium Arene Complexes with α-Aminoacidato Ligands: New Insights into Transfer Hydrogenation Reactions and Cytotoxic Behaviour, file e0d6c92b-2d42-fcf8-e053-d805fe0aa794
|
125
|
|
Ruthenium p-cymene complexes with α-diimine ligands as catalytic precursors for the transfer hydrogenation of ethyl levulinate to γ-valerolactone, file e0d6c92b-24aa-fcf8-e053-d805fe0aa794
|
118
|
|
Synthesis of diiron m-allenyl complexes by electrophilic addition to propen-2-dimetallacyclopentenone species: a joint experimental and DFT study, file e0d6c927-bf28-fcf8-e053-d805fe0aa794
|
115
|
|
Diiron-aminocarbyne complexes with amine or imine ligands: C-N coupling between imine and aminocarbyne ligands promoted by tolylacetilyde addition to [Fe2{m-CN(Me)R}(m-CO)(CO)(NH=CPh2)(Cp)2][SO3CF3], file e0d6c927-c270-fcf8-e053-d805fe0aa794
|
115
|
|
Anticancer Potential of Diiron Vinyliminium Complexes, file e0d6c931-0c5a-fcf8-e053-d805fe0aa794
|
115
|
|
Constructing Organometallic Architectures from Aminoalkylidyne Diiron Complexes, file e0d6c92b-40eb-fcf8-e053-d805fe0aa794
|
108
|
|
C-N coupling between µ-aminocarbyne and nitrile ligands promoted by tolylacetylide addition to [Fe2CN(Me)(Xyl)}(CO)(CO)(NCCMe3)(Cp)2][SO3CF3]: formation of a novel bridging allene-diaminocarbene ligand, file e0d6c927-befa-fcf8-e053-d805fe0aa794
|
103
|
|
Versatile coordination of acetazolamide to ruthenium(II) p-cymene complexes and preliminary cytotoxicity studies, file e0d6c92b-3f1e-fcf8-e053-d805fe0aa794
|
100
|
|
Synthesis, X-Ray Characterization and Reactivity of m-Aminoacidato Ethoxide Complexes of Niobium(V) and Tantalum(V), file e0d6c927-beae-fcf8-e053-d805fe0aa794
|
91
|
|
Bond Forming Reactions Involving Isocyanides at Diiron Complexes, file e0d6c92d-9712-fcf8-e053-d805fe0aa794
|
90
|
|
The reactions of α-amino acids and α-amino acid esters with high valent transition metal halides: synthesis of coordination complexes, activation processes and stabilization of α-ammonium acylchloride cations, file e0d6c928-d4b1-fcf8-e053-d805fe0aa794
|
86
|
|
Controlled Dissociation of Iron and Cyclopentadienyl from a Diiron Complex with a Bridging C3 Ligand Triggered by One-Electron Reduction, file e0d6c92b-3553-fcf8-e053-d805fe0aa794
|
83
|
|
A Strategy to Conjugate Bioactive Fragments to Cytotoxic Diiron Bis(cyclopentadienyl) Complexes, file e0d6c931-5609-fcf8-e053-d805fe0aa794
|
80
|
|
The reactivity of tungsten hexachloride with tetrahydrofuran and 2-methoxyethanol, file e0d6c92d-b17c-fcf8-e053-d805fe0aa794
|
76
|
|
Arene ruthenium (II) complexes with phosphorous ligands as possible anticancer agents, file e0d6c92e-bf11-fcf8-e053-d805fe0aa794
|
71
|
|
α-Diimine homologues of cisplatin: synthesis, speciation in DMSO/water and cytotoxicity, file e0d6c92b-24a7-fcf8-e053-d805fe0aa794
|
70
|
|
Cascade Reactions of α-Phenylcinnamic Acid to Polycyclic Compounds Promoted by High Valent Transition Metal Halides, file e0d6c92b-22e2-fcf8-e053-d805fe0aa794
|
69
|
|
Activation of CN bonds by high-valent group 6 metal chlorides, including the conversion of an α-diimine into a functionalized imidazolium, file e0d6c92b-2b83-fcf8-e053-d805fe0aa794
|
67
|
|
Additions and intramolecular migrations of nucleophiles in cationic diruthenium µ-allenyl complexes, file e0d6c927-c202-fcf8-e053-d805fe0aa794
|
65
|
|
DFT Mechanistic Insights into the Alkyne Insertion Reaction Affording Diiron μ-Vinyliminium Complexes and New Functionalization Pathways, file e0d6c931-2cfd-fcf8-e053-d805fe0aa794
|
63
|
|
Exploring the anticancer potential of diiron bis-cyclopentadienyl complexes with bridging hydrocarbyl ligands: Behavior in aqueous media and in vitro cytotoxicity, file e0d6c931-8fe2-fcf8-e053-d805fe0aa794
|
61
|
|
Acetonitrile activation in diiron µ-carbyne complexes: synthesis and structure of the cyanomethyl complex [Fe2(MU-CNMe2)(CH2CN)(MU-CO)(CO)(Cp)2], file e0d6c927-befd-fcf8-e053-d805fe0aa794
|
59
|
|
Oxidative Dimerization of Triarylamines Promoted by WCl6, Including the Solid State Isolation and the Crystallographic Characterization of a Triphenylammonium Salt, file e0d6c930-deec-fcf8-e053-d805fe0aa794
|
51
|
|
Heterotrimetallic complexes of iron and ruthenium based on vinyliminium dithiocarboxylate ligands, file e0d6c92d-a357-fcf8-e053-d805fe0aa794
|
49
|
|
Tethering Carbohydrates to the Vinyliminium Ligand of Antiproliferative Organometallic Diiron Complexes, file 51425a1f-be77-4862-8fdb-d1d1ae2665cd
|
46
|
|
Decarbonylation of phenylacetic acids by high valent transition metal halides, file e0d6c931-03fe-fcf8-e053-d805fe0aa794
|
45
|
|
Metal N,N-dialkylcarbamates as easily available catalytic precursors for the carbon dioxide/propylene oxide coupling under ambient conditions, file e0d6c931-0a46-fcf8-e053-d805fe0aa794
|
45
|
|
The chlorinating behaviour of WCl6 towards α-aminoacids, file e0d6c931-30e7-fcf8-e053-d805fe0aa794
|
45
|
|
null, file 782b0d91-4126-4add-954f-0451c61e0982
|
43
|
|
Tuning the cytotoxicity of ruthenium(ii) para-cymene complexes by mono-substitution at a triphenylphosphine/phenoxydiphenylphosphine ligand, file e0d6c930-7bd6-fcf8-e053-d805fe0aa794
|
43
|
|
Carboxylation of Terminal Alkynes Promoted by Silver Carbamate at Ambient Pressure, file e0d6c931-088b-fcf8-e053-d805fe0aa794
|
41
|
|
Stable coordination complexes of α-diimines with Nb(v) and Ta(v) halides, file e0d6c931-1690-fcf8-e053-d805fe0aa794
|
40
|
|
Synthesis of new coordination complexes of MF5(M = Nb, Ta), and insights into the Ta(V) reduction, file e0d6c92b-3f21-fcf8-e053-d805fe0aa794
|
38
|
|
Exploring the anticancer potential of diiron bis-cyclopentadienyl complexes with bridging hydrocarbyl ligands: Behavior in aqueous media and in vitro cytotoxicity, file e0d6c92f-1894-fcf8-e053-d805fe0aa794
|
38
|
|
Alkyne-alkenyl coupling at a diruthenium complex, file 8a15c5c2-e27c-46c2-80de-721848ad3a01
|
33
|
|
Synthesis and study of the stability of amidinium/guanidinium carbamates of amines and α-amino acids, file e0d6c92f-026f-fcf8-e053-d805fe0aa794
|
31
|
|
Synthesis of α-amino acidato derivatives of niobium and tantalum pentahalides and their conversion into iminium salts, file e0d6c931-2e59-fcf8-e053-d805fe0aa794
|
31
|
|
Straightforward formation of carbocations from tertiary carboxylic acids via CO release at room temperature, file e0d6c931-26b7-fcf8-e053-d805fe0aa794
|
29
|
|
null, file 5e1473e8-cc58-440c-8285-395fcf99dd65
|
28
|
| Totale |
18.009 |