Nome |
# |
Revisitation of the PCl5-chlorination reaction of a-amino acids: Spectroscopic and DFT insights, and synthesis of the L-proline-derived 2,5-diketopiperazine, file e0d6c927-c400-fcf8-e053-d805fe0aa794
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1.790
|
The chemistry of high valent tungsten chlorides with N-substituted ureas, including urea self-protonation reactions triggered by WCl6, file e0d6c927-be1f-fcf8-e053-d805fe0aa794
|
608
|
Synthesis of a highly reactive form of WO2Cl2, its conversion into nanocrystalline mono-hydrated WO3 and coordination compounds with tetramethylurea, file e0d6c927-be20-fcf8-e053-d805fe0aa794
|
425
|
19F NMR spectroscopy as useful tool for determining the structure in solution of coordination compounds of MF5 (M = Nb, Ta), file e0d6c927-c02d-fcf8-e053-d805fe0aa794
|
390
|
Structural Characterization of a Fluorido-Amide of Niobium, and Facile CO2 Incorporation Affording a Fluorido-Carbamate, file e0d6c92a-9fe9-fcf8-e053-d805fe0aa794
|
387
|
The versatile chemistry of niobium pentachloride with aliphatic amines: Aminolysis, metal reduction and C–H activation, file e0d6c927-be72-fcf8-e053-d805fe0aa794
|
371
|
Room-temperature polymerization of beta-pinene by niobium and tantalum halides, file e0d6c927-c698-fcf8-e053-d805fe0aa794
|
353
|
A Crystallographic and Spectroscopic Study of the Reactions of WCl6 with Carbonyl Compounds, file e0d6c927-c089-fcf8-e053-d805fe0aa794
|
344
|
The reactivity of MoCl5 with molecules containing the alcohol functionality, file e0d6c927-be84-fcf8-e053-d805fe0aa794
|
340
|
Ligand-interchange reactions between M(iv) (M = Ti, V) oxide bis-acetylacetonates and halides of high-valent group 4 and 5 metals. A synthetic and electrochemical study, file e0d6c927-bea4-fcf8-e053-d805fe0aa794
|
294
|
Halo-complexes of Titanium(III): the Thermochromic Behaviour of [NBu4][TiCl4(thf)2], file e0d6c927-c024-fcf8-e053-d805fe0aa794
|
282
|
Molybdenum(V) and Molybdenum(IV) coordination compounds from the reaction of MoCl5 with sulfones, file e0d6c926-9090-fcf8-e053-d805fe0aa794
|
281
|
Epoxide Ring Opening and Insertion into the M–X Bond of Niobium and Tantalum Pentahalides: Synthesis of Dihalide-tris(2-haloalcoholato) Complexes, file e0d6c927-c78f-fcf8-e053-d805fe0aa794
|
279
|
Different outcomes in the reactions of WCl6 with carboxylic acids, file e0d6c927-bdfc-fcf8-e053-d805fe0aa794
|
271
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Coordination complexes of niobium and tantalum pentahalides with a bulky NHC ligand, file e0d6c927-c1a4-fcf8-e053-d805fe0aa794
|
267
|
A crystallographic and DFT study on a NHC complex of niobium oxide trifluoride, file e0d6c927-c133-fcf8-e053-d805fe0aa794
|
248
|
null, file e0d6c927-c405-fcf8-e053-d805fe0aa794
|
244
|
The chemistry of Niobium and Tantalum halides, MX5, with haloacetic acids and their related anhydrides: anhydride C–H bond activation promoted by MF5, file e0d6c927-c106-fcf8-e053-d805fe0aa794
|
238
|
A general strategy to add diversity to ruthenium arene complexes with bioactive organic compounds: Via a coordinated (4-hydroxyphenyl)diphenylphosphine ligand, file e0d6c929-c7f0-fcf8-e053-d805fe0aa794
|
225
|
Further Insights into the Chemistry of Niobium and Tantalum Pentahalides with 1,2-Dialkoxyalkanes: Synthesis of Bromo- and Iodoalkoxides, Spectroscopic and Computational Studies, file e0d6c927-bfb3-fcf8-e053-d805fe0aa794
|
218
|
null, file e0d6c927-ad0d-fcf8-e053-d805fe0aa794
|
217
|
One pot conversion of benzophenone imine into the relevant 2-aza-allenium, file e0d6c929-dbd3-fcf8-e053-d805fe0aa794
|
216
|
Coordination Compounds of Niobium(IV) Oxide Dihalides Including the Synthesis and the Crystallographic Characterization of NHC Complexes, file e0d6c927-c770-fcf8-e053-d805fe0aa794
|
215
|
Modifying bis(triflimide) ionic liquids by dissolving early transition metal carbamates, file e0d6c92a-157b-fcf8-e053-d805fe0aa794
|
213
|
Reactions of TaF5 with Activated Arenes. Synthesis of [4-(OH)-3-(OCH3)C6H3CH(=O-H)][4-(OH)-3-(OCH3)C6H3CHO][TaF6], a Rare Example of Protonated Aldehyde, file e0d6c927-c5a1-fcf8-e053-d805fe0aa794
|
204
|
null, file e0d6c929-dd4f-fcf8-e053-d805fe0aa794
|
204
|
Synthesis, characterization and behavior in water/DMSO solution of Ru(II) arene complexes with bioactive carboxylates, file e0d6c92b-3f1c-fcf8-e053-d805fe0aa794
|
203
|
null, file e0d6c927-bfa3-fcf8-e053-d805fe0aa794
|
202
|
One pot conversion of acetyl chloride to dehydroacetic acid and its coordination in a ruthenium(II) arene complex, file e0d6c929-a717-fcf8-e053-d805fe0aa794
|
199
|
Vanadium(v) oxoanions in basic water solution: A simple oxidative system for the one pot selective conversion of l-proline to pyrroline-2-carboxylate, file e0d6c92a-0c6d-fcf8-e053-d805fe0aa794
|
193
|
Regioselective Nucleophilic Additions to Diiron Carbonyl Complexes Containing a Bridging Aminocarbyne Ligand: A Synthetic, Crystallographic and DFT Study, file e0d6c92a-8963-fcf8-e053-d805fe0aa794
|
190
|
Characterization and Thermal Activation of Adducts of Group 4 Tetrahalides with 1,2-Dialkoxyalkanes, file e0d6c927-c030-fcf8-e053-d805fe0aa794
|
189
|
Dioxomolybdenum(VI) compounds with α-amino acid donor ligands as catalytic precursors for the selective oxyfunctionalization of olefins, file e0d6c92a-8b42-fcf8-e053-d805fe0aa794
|
182
|
Iron(III) N,N-Dialkylcarbamate-Catalyzed Formation of Cyclic Carbonates from CO2 and Epoxides under Ambient Conditions by Dynamic CO2 Trapping as Carbamato Ligands, file e0d6c930-de26-fcf8-e053-d805fe0aa794
|
182
|
Electron exchange reactions between tungsten hexachloride and nitrogen donors, file e0d6c927-bdf8-fcf8-e053-d805fe0aa794
|
174
|
Anticancer Potential of Diiron Vinyliminium Complexes, file e0d6c92e-b944-fcf8-e053-d805fe0aa794
|
172
|
Synthesis and Antiproliferative Activity of New Ruthenium Complexes with Ethacrynic-Acid-Modified Pyridine and Triphenylphosphine Ligands, file e0d6c927-be00-fcf8-e053-d805fe0aa794
|
166
|
Unusual activation pathways of amines in the reactions with molybdenum pentachloride, file e0d6c929-dbd4-fcf8-e053-d805fe0aa794
|
165
|
The reactivity of niobium and tantalum pentahalides with imines, file e0d6c927-c672-fcf8-e053-d805fe0aa794
|
159
|
Allowing the direct interaction of: N -aryl α-diimines with a high valent metal chloride: One-pot WCl6-promoted formation of quinoxalinium salts, file e0d6c929-98bd-fcf8-e053-d805fe0aa794
|
159
|
Oxido- and Sulfidoniobium(V) N,N-Diethylcarbamates: Synthesis, Characterization and DFT Study, file e0d6c927-bea9-fcf8-e053-d805fe0aa794
|
157
|
Synthesis, variable temperature NMR investigations and solid state characterisation of novel octafluorofluorene compounds, file e0d6c927-c0a9-fcf8-e053-d805fe0aa794
|
151
|
Piano Stool Aminoalkylidene-Ferracyclopentenone Complexes from Bimetallic Precursors: Synthesis and Cytotoxicity Data, file e0d6c92e-6772-fcf8-e053-d805fe0aa794
|
145
|
Synthesis and spectroscopic/DFT structural characterization of coordination compounds of Nb(V) and Ti(IV) with bioactive carboxylic acids, file e0d6c92a-a2cf-fcf8-e053-d805fe0aa794
|
139
|
Synthesis and Structural Characterization of Non-Homoleptic Carbamato Complexes of V(V) and W(VI) and Their Facile Implantation onto Silica Surfaces, file e0d6c92a-a543-fcf8-e053-d805fe0aa794
|
139
|
Diiron Complexes with a Bridging Functionalized Allylidene Ligand: Synthesis, Structural Aspects, and Cytotoxicity, file e0d6c92f-224b-fcf8-e053-d805fe0aa794
|
130
|
Ruthenium Arene Complexes with α-Aminoacidato Ligands: New Insights into Transfer Hydrogenation Reactions and Cytotoxic Behaviour, file e0d6c92b-2d42-fcf8-e053-d805fe0aa794
|
124
|
Ruthenium p-cymene complexes with α-diimine ligands as catalytic precursors for the transfer hydrogenation of ethyl levulinate to γ-valerolactone, file e0d6c92b-24aa-fcf8-e053-d805fe0aa794
|
117
|
Anticancer Potential of Diiron Vinyliminium Complexes, file e0d6c931-0c5a-fcf8-e053-d805fe0aa794
|
117
|
Synthesis of diiron m-allenyl complexes by electrophilic addition to propen-2-dimetallacyclopentenone species: a joint experimental and DFT study, file e0d6c927-bf28-fcf8-e053-d805fe0aa794
|
111
|
Versatile coordination of acetazolamide to ruthenium(II) p-cymene complexes and preliminary cytotoxicity studies, file e0d6c92b-3f1e-fcf8-e053-d805fe0aa794
|
99
|
Synthesis and spectroscopic characterization of titanium pyridylanilido complexes as catalysts for the polymerization of 1,3-butadiene and isoprene, file e0d6c92b-87a0-fcf8-e053-d805fe0aa794
|
96
|
Synthesis, X-Ray Characterization and Reactivity of m-Aminoacidato Ethoxide Complexes of Niobium(V) and Tantalum(V), file e0d6c927-beae-fcf8-e053-d805fe0aa794
|
90
|
The reactions of α-amino acids and α-amino acid esters with high valent transition metal halides: synthesis of coordination complexes, activation processes and stabilization of α-ammonium acylchloride cations, file e0d6c928-d4b1-fcf8-e053-d805fe0aa794
|
88
|
THERMAL DECOMPOSITION OF METAL N,N-DIALKYLCARBAMATES: A TG-FTIR STUDY, file e0d6c927-5f51-fcf8-e053-d805fe0aa794
|
84
|
Controlled Dissociation of Iron and Cyclopentadienyl from a Diiron Complex with a Bridging C3 Ligand Triggered by One-Electron Reduction, file e0d6c92b-3553-fcf8-e053-d805fe0aa794
|
82
|
A Strategy to Conjugate Bioactive Fragments to Cytotoxic Diiron Bis(cyclopentadienyl) Complexes, file e0d6c931-5609-fcf8-e053-d805fe0aa794
|
79
|
The reactivity of tungsten hexachloride with tetrahydrofuran and 2-methoxyethanol, file e0d6c92d-b17c-fcf8-e053-d805fe0aa794
|
72
|
α-Diimine homologues of cisplatin: synthesis, speciation in DMSO/water and cytotoxicity, file e0d6c92b-24a7-fcf8-e053-d805fe0aa794
|
70
|
Arene ruthenium (II) complexes with phosphorous ligands as possible anticancer agents, file e0d6c92e-bf11-fcf8-e053-d805fe0aa794
|
70
|
Cascade Reactions of α-Phenylcinnamic Acid to Polycyclic Compounds Promoted by High Valent Transition Metal Halides, file e0d6c92b-22e2-fcf8-e053-d805fe0aa794
|
69
|
Activation of CN bonds by high-valent group 6 metal chlorides, including the conversion of an α-diimine into a functionalized imidazolium, file e0d6c92b-2b83-fcf8-e053-d805fe0aa794
|
67
|
Exploring the anticancer potential of diiron bis-cyclopentadienyl complexes with bridging hydrocarbyl ligands: Behavior in aqueous media and in vitro cytotoxicity, file e0d6c931-8fe2-fcf8-e053-d805fe0aa794
|
61
|
Oxidative Dimerization of Triarylamines Promoted by WCl6, Including the Solid State Isolation and the Crystallographic Characterization of a Triphenylammonium Salt, file e0d6c930-deec-fcf8-e053-d805fe0aa794
|
56
|
Metal N,N-dialkylcarbamates as easily available catalytic precursors for the carbon dioxide/propylene oxide coupling under ambient conditions, file e0d6c931-0a46-fcf8-e053-d805fe0aa794
|
45
|
The chlorinating behaviour of WCl6 towards α-aminoacids, file e0d6c931-30e7-fcf8-e053-d805fe0aa794
|
45
|
Tuning the cytotoxicity of ruthenium(ii) para-cymene complexes by mono-substitution at a triphenylphosphine/phenoxydiphenylphosphine ligand, file e0d6c930-7bd6-fcf8-e053-d805fe0aa794
|
44
|
Decarbonylation of phenylacetic acids by high valent transition metal halides, file e0d6c931-03fe-fcf8-e053-d805fe0aa794
|
41
|
Stable coordination complexes of α-diimines with Nb(v) and Ta(v) halides, file e0d6c931-1690-fcf8-e053-d805fe0aa794
|
41
|
Carboxylation of Terminal Alkynes Promoted by Silver Carbamate at Ambient Pressure, file e0d6c931-088b-fcf8-e053-d805fe0aa794
|
39
|
Exploring the anticancer potential of diiron bis-cyclopentadienyl complexes with bridging hydrocarbyl ligands: Behavior in aqueous media and in vitro cytotoxicity, file e0d6c92f-1894-fcf8-e053-d805fe0aa794
|
38
|
Synthesis of new coordination complexes of MF5(M = Nb, Ta), and insights into the Ta(V) reduction, file e0d6c92b-3f21-fcf8-e053-d805fe0aa794
|
37
|
Synthesis of α-amino acidato derivatives of niobium and tantalum pentahalides and their conversion into iminium salts, file e0d6c931-2e59-fcf8-e053-d805fe0aa794
|
33
|
Alkyne-alkenyl coupling at a diruthenium complex, file 8a15c5c2-e27c-46c2-80de-721848ad3a01
|
32
|
Synthesis and study of the stability of amidinium/guanidinium carbamates of amines and α-amino acids, file e0d6c92f-026f-fcf8-e053-d805fe0aa794
|
32
|
Straightforward formation of carbocations from tertiary carboxylic acids via CO release at room temperature, file e0d6c931-26b7-fcf8-e053-d805fe0aa794
|
32
|
null, file 5e1473e8-cc58-440c-8285-395fcf99dd65
|
29
|
When ferrocene and diiron organometallics meet: triiron vinyliminium complexes exhibit strong cytotoxicity and cancer cell selectivity, file 4e63ad65-0aee-40e0-b718-abcd4d56382b
|
25
|
Synthesis and structural characterization of mixed halide–N,N-diethylcarbamates of group 4 metals, including a case of unusual tetrahydrofuran activation, file e0d6c92e-fa06-fcf8-e053-d805fe0aa794
|
25
|
A crystallographically characterized salt of self-generated N-protonated tetraethylurea, file e0d6c931-3a42-fcf8-e053-d805fe0aa794
|
23
|
Non-precious metal carbamates as catalysts for the aziridine/CO2coupling reaction under mild conditions, file e0d6c931-797f-fcf8-e053-d805fe0aa794
|
18
|
Carbon-Carbon Bond Coupling of Vinyl Molecules with an Allenyl Ligand at a Diruthenium Complex, file 53ed26ce-dc1e-43bc-bbf0-259c7013cf34
|
15
|
Diethylammonium iodide as catalyst for the metal-free synthesis of 5-aryl-2-oxazolidinones from aziridines and carbon dioxide, file e0d6c931-920d-fcf8-e053-d805fe0aa794
|
14
|
Synthesis of α-alkylidene cyclic carbonatesviaCO2fixation under ambient conditions promoted by an easily available silver carbamate, file e0d6c931-6a9a-fcf8-e053-d805fe0aa794
|
13
|
Activation reactions of 1,1-dialkoxoalkanes and unsaturated O-donors by titanium tetrafluoride, file fe9ffb13-a47b-4f35-93e7-553b9e9a60ba
|
11
|
Anticancer diiron vinyliminium complexes: A structure– activity relationship study, file e0d6c931-4ed7-fcf8-e053-d805fe0aa794
|
10
|
A comparative structural and spectroscopic study of diiron and diruthenium isocyanide and aminocarbyne complexes, file e0d6c932-4301-fcf8-e053-d805fe0aa794
|
9
|
THERMAL DECOMPOSITION OF METAL N,N-DIALKYLCARBAMATES: A TG-FTIR STUDY, file e0d6c927-59da-fcf8-e053-d805fe0aa794
|
8
|
Role of the (pseudo)halido ligand in ruthenium(ii): p -cymene a-amino acid complexes in speciation, protein reactivity and cytotoxicity, file e0d6c931-8984-fcf8-e053-d805fe0aa794
|
8
|
Titanium Complexes Bearing Carbamato Ligands as Catalytic Precursorsfor Propylene Polymerization Reactions, file e0d6c926-d218-fcf8-e053-d805fe0aa794
|
7
|
Recent advances in the chemistry of metal carbamates, file e0d6c92f-47a4-fcf8-e053-d805fe0aa794
|
7
|
Trapping carbamates of α-Amino acids: One-Pot and catalyst-free synthesis of 5-Aryl-2-Oxazolidinonyl derivatives, file e0d6c931-6a9c-fcf8-e053-d805fe0aa794
|
7
|
Carbonyl-isocyanide mono-substitution in [Fe2Cp2(CO)4]: A re-visitation, file e0d6c931-6f76-fcf8-e053-d805fe0aa794
|
7
|
Conjugating Biotin to Ruthenium(II) Arene Units via Phosphine Ligand Functionalization, file e0d6c92f-1896-fcf8-e053-d805fe0aa794
|
6
|
Serendipitous Formation of a Zwitterionic Imidazolium Molecule from α-Diimine with Glyoxal as Unusual Cyclization Agent, file e0d6c931-8558-fcf8-e053-d805fe0aa794
|
6
|
Total- and semi-bare noble metal nanoparticles@silica core@shell catalysts for hydrogen generation by formic acid decomposition, file e0d6c931-a810-fcf8-e053-d805fe0aa794
|
6
|
Cyanide-alkene competition in a diiron complex and isolation of a multisite (cyano)alkylidene-alkene species, file e0d6c932-42a9-fcf8-e053-d805fe0aa794
|
6
|
Stable [M2F11]– (M = Nb, Ta) Salts of Protonated 1,3-Dimethoxybenzene, file e0d6c927-66d9-fcf8-e053-d805fe0aa794
|
5
|
Anticancer Potential of Diiron Vinyliminium Complexes, file e0d6c930-5654-fcf8-e053-d805fe0aa794
|
5
|
Easily Available, Amphiphilic Diiron Cyclopentadienyl Complexes Exhibit in Vitro Anticancer Activity in 2D and 3D Human Cancer Cells through Redox Modulation Triggered by CO Release, file e0d6c931-4ecd-fcf8-e053-d805fe0aa794
|
5
|
Totale |
14.806 |