Asoundsynthetic procedure for the preparation of trans-[PtBr(μ-Br)(PPh3)]2is described. The species was fully characterized and used to obtain [PtBr2(PPh3)(L)] complexes (L = DMSO, p-toluidine, pyridine) by a bridge-splitting reaction. All productswere fully characterized by NMR spectroscopy, together with cis-[PtBr2(PPh3)(NCCH3)], obtained as an intermediatein the synthesis of the dinuclear precursor. Cis-[PtBr2(PPh3)(NCCH3)] was also studied by x-ray diffraction.
A sound sequence to triphenylphosphino dibromoplatinum(II) complexes. Solvothermal preparation of trans-[PtBr(μ-Br)(PPh3)]2
Daniela Belli Dell' Amico;luca Labella;Fabio Marchetti;Simona Samaritani
Ultimo
2019-01-01
Abstract
Asoundsynthetic procedure for the preparation of trans-[PtBr(μ-Br)(PPh3)]2is described. The species was fully characterized and used to obtain [PtBr2(PPh3)(L)] complexes (L = DMSO, p-toluidine, pyridine) by a bridge-splitting reaction. All productswere fully characterized by NMR spectroscopy, together with cis-[PtBr2(PPh3)(NCCH3)], obtained as an intermediatein the synthesis of the dinuclear precursor. Cis-[PtBr2(PPh3)(NCCH3)] was also studied by x-ray diffraction.File in questo prodotto:
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