Direct arylation of 5-octylthieno[3,4-dpyrrole-4,6-dione with a series of functionalized aryl iodides via C-H bond activation is demonstrated in a deep eutectic solvent made of choline chloride and urea in non-anhydrous conditions and without exclusion of air. This is the first demonstration of a thiophene aryl coupling via direct arylation in deep eutectic solvents.
Pd-Catalyzed Thiophene-Aryl Coupling Reaction via C-H Bond Activation in Deep Eutectic Solvents
Operamolla Alessandra;
2017-01-01
Abstract
Direct arylation of 5-octylthieno[3,4-dpyrrole-4,6-dione with a series of functionalized aryl iodides via C-H bond activation is demonstrated in a deep eutectic solvent made of choline chloride and urea in non-anhydrous conditions and without exclusion of air. This is the first demonstration of a thiophene aryl coupling via direct arylation in deep eutectic solvents.File in questo prodotto:
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23. Org. lett. 2017.pdf
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