Copper (I) iodide absorbs carbon monoxide in methanol in the presence of ethylenediamine (en), giving solutions from which [Cu2(en)3(CO)2]I2, [Cu2(en)3(CO)2](BPh4)2, and [Cu(en)2CO]I have been obtained as thermally stable compounds; the reaction of CuCOCl with en allowed the isolation of [Cu(en)(CO)PhBPh3], an X-ray structure determination of which shows the presence of a three-co-ordinate copper(I) interacting with the BPh4– anion.
Coppper(I) ethylenediamine carbonyl complexes: ‘models’ for carbon monoxide activation. X-Ray structure of the ion-pair carbonylethylenediaminetetraphenylboratocopper
PASQUALI, MARCO;
1978-01-01
Abstract
Copper (I) iodide absorbs carbon monoxide in methanol in the presence of ethylenediamine (en), giving solutions from which [Cu2(en)3(CO)2]I2, [Cu2(en)3(CO)2](BPh4)2, and [Cu(en)2CO]I have been obtained as thermally stable compounds; the reaction of CuCOCl with en allowed the isolation of [Cu(en)(CO)PhBPh3], an X-ray structure determination of which shows the presence of a three-co-ordinate copper(I) interacting with the BPh4– anion.File in questo prodotto:
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