The 2:1 reaction of [Ru(H2O)(2)(NH3)(5)](2+) with 1,2,4,5-tetrazine (tz) gives rise to the formation of the dinuclear complex ion [{Ru(NH3)(5)}(2)(mu-tz-N-1:N-4)](4+). Its tetraphenylborate and hexafluoro-phosphate salts have been fully characterized; the X-ray structure of the former has also been determined.
mu-1,2,4,5-Tetrazine-N1:N4-bis(pentaammineruthenium) Tetracation: Synthesis and X-ray Structure
DENTI, GIANFRANCO
2007-01-01
Abstract
The 2:1 reaction of [Ru(H2O)(2)(NH3)(5)](2+) with 1,2,4,5-tetrazine (tz) gives rise to the formation of the dinuclear complex ion [{Ru(NH3)(5)}(2)(mu-tz-N-1:N-4)](4+). Its tetraphenylborate and hexafluoro-phosphate salts have been fully characterized; the X-ray structure of the former has also been determined.File in questo prodotto:
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