The crystal structure of the nanocrystalline alpha phase of Pigment Yellow 213 (P.Y. 213) was solved by a combination of single-crystal electron diffraction and X-ray powder diffraction, despite the poor crystalinity of the material. The molecules from an efficient dense packing, which explains the observed insolubility and weather fastness of the pigment. The pair-distribution function (PDF) of the alpha phase is consistent with the determined crystal structure. The beta phase of P.Y. 213 shows even lower crystal quality, so extracting any structural information directly from the diffraction data is not possible. PDF analysis indicates the beta phase to have a columnar structure with a similar local structrue as the alpha phase and a domain size in column direction of approximately 4 nm. RI Kolb, Ute/A-2642-2011; Mugnaioli, Enrico/E-6237-2011; van de Streek, Jacco/B-3164-2012; Brunelli, Michela/A-5925-2013
Electron diffraction, X-ray powder diffraction and pair-distribution-function analyses to determine the crystal structure of Pigment Yellow 213, C23H21N5O9
Mugnaioli E;
2009-01-01
Abstract
The crystal structure of the nanocrystalline alpha phase of Pigment Yellow 213 (P.Y. 213) was solved by a combination of single-crystal electron diffraction and X-ray powder diffraction, despite the poor crystalinity of the material. The molecules from an efficient dense packing, which explains the observed insolubility and weather fastness of the pigment. The pair-distribution function (PDF) of the alpha phase is consistent with the determined crystal structure. The beta phase of P.Y. 213 shows even lower crystal quality, so extracting any structural information directly from the diffraction data is not possible. PDF analysis indicates the beta phase to have a columnar structure with a similar local structrue as the alpha phase and a domain size in column direction of approximately 4 nm. RI Kolb, Ute/A-2642-2011; Mugnaioli, Enrico/E-6237-2011; van de Streek, Jacco/B-3164-2012; Brunelli, Michela/A-5925-2013I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.