Hybrids of cationic [4]helicene and N-heterocyclic carbene as ligands for complexes exhibiting (chir)optical properties in the far red spectral window

Synthesis, electronic and structural properties of a chiral NHC bearing a N-bonded cationic [4]helicene moiety are reported. This ligand is used to construct Au-I, Au-III and Rh-I complexes exhibiting far-red (chir)optical properties regardless of the metal.