Graulichite-(La), LaFe33+(AsO4)(2)(OH)(6), a new addition to the alunite supergroup from the Patte d'Oie mine, Bou Skour mining district, Morocco

The new mineral species graulichite-(La), ideally LaFe33+(AsO4)(2)(OH)(6), has been discovered in the Patte d'Oie mine, Bou Skour mining district, Morocco. It occurs as yellow rhombohedral crystals, up to 0.1 mm in size, with a resinous luster, associated with malachite, agardite(La), conichalcite, and a still undetermined REE carbonate. Crystals are chemically zoned and two homogeneous domains were identified, corresponding to the empirical chemical formulae (calculated on the basis of 6 cations per formula unit, assuming the occurrence of 14 O atoms) (La0.34Ce0.20Ca0.11Sr0.07Pb0.05K0.04)(Sigma 0.81)(Fe2.163+Al0.84Cu0.20)(Sigma 3.20)(As1.23P0.39S0.37)(Sigma 1.99)O14H6.13 (domain #1) and (La0.38Ce0.22Sr0.10Ca0.09Pb0.05K0.06)(Sigma 0.90)(Fe2.603+Al0.49Cu0.20)(Sigma 3.29)(AS(0.91)P(0.50)S(0.40))(Sigma 1.81) O14H6.53 (domain #2). Single-crystal unit-cell parameters are a = 7.252(13), c = 16.77(3) angstrom, V = 764(3) angstrom(3), space group R-3m. The eight strongest reflections in the observed X-ray powder diffraction pattern are (d in angstrom, visually estimated intensity): 5.86, medium; 3.045, strong; 2.511, medium-weak; 2.239, medium; 1.960, medium-weak; 1.813, medium-weak; 1.689, medium-weak; 1.478, medium. Graulichite-(La) belongs to the dussertite group within the alunite supergroup. It is the La analogue of graulichite-(Ce) and the Fe3+ analogue of arsenoflorencite-(La).