Reaction of [Mo(CO)3(C6H5Me)] with o-phenylenediamine and phthalaldehyde carried out in methanol at room temperature gives [Mo(CO)3L]{L = 2-[(2′-aminophenyl)iminomethyl]benzaldehydea. The molecular structure determination of [Mo(CO)3L] shows the open-chain nature of L together with the η2-co-ordination of the aldehydic group to the metal. The compound is an openchain intermediate for a N4 macrocyclic complex.
Autori interni: | ||
Autori: | LEONI P; GRILLI E; PASQUALI M; TOMASSINI M | |
Titolo: | Condensation of o-phenylenediamine and phthalaldehyde using molybdenum(0) as template. Isolation and crystal and molecular structure of an intermediate molybdenum complex with an 2-bonded aldehydic | |
Anno del prodotto: | 1986 | |
Digital Object Identifier (DOI): | 10.1039/DT9860000879 | |
Appare nelle tipologie: | 1.1 Articolo in rivista |
File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.