Reaction of [Mo(CO)3(C6H5Me)] with o-phenylenediamine and phthalaldehyde carried out in methanol at room temperature gives [Mo(CO)3L]{L = 2-[(2′-aminophenyl)iminomethyl]benzaldehydea. The molecular structure determination of [Mo(CO)3L] shows the open-chain nature of L together with the η2-co-ordination of the aldehydic group to the metal. The compound is an openchain intermediate for a N4 macrocyclic complex.
Condensation of o-phenylenediamine and phthalaldehyde using molybdenum(0) as template. Isolation and crystal and molecular structure of an intermediate molybdenum complex with an 2-bonded aldehydic
LEONI, PIERO;PASQUALI, MARCO;
1986-01-01
Abstract
Reaction of [Mo(CO)3(C6H5Me)] with o-phenylenediamine and phthalaldehyde carried out in methanol at room temperature gives [Mo(CO)3L]{L = 2-[(2′-aminophenyl)iminomethyl]benzaldehydea. The molecular structure determination of [Mo(CO)3L] shows the open-chain nature of L together with the η2-co-ordination of the aldehydic group to the metal. The compound is an openchain intermediate for a N4 macrocyclic complex.File in questo prodotto:
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