The reaction of easily available stereoisomeric mixtures of 1-alkenyl bromides with molar excesses of trialkylstannyl phenyl sulfides takes place readily in the presence of Pd(PPH3)4 to afford diastereoselectively (E)-1-alkenyl phenyl sulfides in excellent yields.
Palladium-catalyzed reactions of trialkylstannyl phenyl sulfides with alkenyl bromides. A new diastereoselective synthesis of (E)-1-alkenyl phenyl sulfides
CARPITA, ADRIANO;ROSSI, RENZO;
1989-01-01
Abstract
The reaction of easily available stereoisomeric mixtures of 1-alkenyl bromides with molar excesses of trialkylstannyl phenyl sulfides takes place readily in the presence of Pd(PPH3)4 to afford diastereoselectively (E)-1-alkenyl phenyl sulfides in excellent yields.File in questo prodotto:
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