Chemoresponsive microgels functionalized with enantiomeric Delta- or Lambda-[Ru(bpy)(3)](2+) showed tunable chiroptical properties upon swelling and shrinking. The tuning is triggered by a modulation of the local mobility of [Ru(bpy)(3)](2+) upon addition of fructose, controlling interactions and distances between [Ru(bpy)(3)](2+) and phenylboronic acid.
Modulation of circularly polarized luminescence by swelling of microgels functionalized with enantiopure [Ru(bpy)3]2+ luminophores
Zinna, Francesco;Lacour, Jérôme;
2024-01-01
Abstract
Chemoresponsive microgels functionalized with enantiomeric Delta- or Lambda-[Ru(bpy)(3)](2+) showed tunable chiroptical properties upon swelling and shrinking. The tuning is triggered by a modulation of the local mobility of [Ru(bpy)(3)](2+) upon addition of fructose, controlling interactions and distances between [Ru(bpy)(3)](2+) and phenylboronic acid.File in questo prodotto:
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