(5-Acetyl-2-thienyl)(5-benzoyl-2-thienyl)(5-bromo-2-thienyl)-(5-cyano-2-thienyl)methane has been synthesized as the first chiral tetrakis(2-thienyl)methane derivative. This compound can be resolved by chiral HPLC. Since Raney nickel reduction of tetrakis(2-thienyl)methane derivatives gave tetraalkylmethane derivatives, chiral tetrakis(2-thienyl)methane derivatives will be good precursors for a number of cryptochiral tetraalkylmethanes and their derivatives.

Chiral Tetrakis(2-thienyl)methane Derivative: A Possible Precursor for Cryptochiral Tetraalkylmethanes

PESCITELLI, GENNARO;
2008-01-01

Abstract

(5-Acetyl-2-thienyl)(5-benzoyl-2-thienyl)(5-bromo-2-thienyl)-(5-cyano-2-thienyl)methane has been synthesized as the first chiral tetrakis(2-thienyl)methane derivative. This compound can be resolved by chiral HPLC. Since Raney nickel reduction of tetrakis(2-thienyl)methane derivatives gave tetraalkylmethane derivatives, chiral tetrakis(2-thienyl)methane derivatives will be good precursors for a number of cryptochiral tetraalkylmethanes and their derivatives.
2008
Matsumoto, K; Miki, K; Kurata, H; Rikitake, N; Nehira, T; Inagaki, T; Pescitelli, Gennaro; Yasukazu, H; Kawase, T; Oda, M; Kubo, T.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11568/125592
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