(5-Acetyl-2-thienyl)(5-benzoyl-2-thienyl)(5-bromo-2-thienyl)-(5-cyano-2-thienyl)methane has been synthesized as the first chiral tetrakis(2-thienyl)methane derivative. This compound can be resolved by chiral HPLC. Since Raney nickel reduction of tetrakis(2-thienyl)methane derivatives gave tetraalkylmethane derivatives, chiral tetrakis(2-thienyl)methane derivatives will be good precursors for a number of cryptochiral tetraalkylmethanes and their derivatives.
Autori interni: | ||
Autori: | MATSUMOTO K; MIKI K; KURATA H; RIKITAKE N; NEHIRA T; INAGAKI T; PESCITELLI G; YASUKAZU H; KAWASE T; ODA M; KUBO T | |
Titolo: | Chiral Tetrakis(2-thienyl)methane Derivative: A Possible Precursor for Cryptochiral Tetraalkylmethanes | |
Anno del prodotto: | 2008 | |
Digital Object Identifier (DOI): | 10.1246/cl.2008.1236 | |
Appare nelle tipologie: | 1.1 Articolo in rivista |
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