Reaction of [Pt(6)(CO)(4)(P(t)Bu(2))(4)Cl(2)] with excess HS(CH(2))(4)SH in Et(2)NH gave highly stable [Pt(6)(CO)(4)(PtBu(2))(4){S(CH(2))(4)SH}(2)], which adsorbs unchanged onto gold surfaces. This permitted the fabrication and electrical characterisation of gold|molecule|gold junctions involving a well-defined metal carbonyl cluster compound.

A Molecular Wire Incorporating a Robust Hexanuclear Platinum Cluster

LEONI, PIERO;MARCHETTI, LORELLA;
2009-01-01

Abstract

Reaction of [Pt(6)(CO)(4)(P(t)Bu(2))(4)Cl(2)] with excess HS(CH(2))(4)SH in Et(2)NH gave highly stable [Pt(6)(CO)(4)(PtBu(2))(4){S(CH(2))(4)SH}(2)], which adsorbs unchanged onto gold surfaces. This permitted the fabrication and electrical characterisation of gold|molecule|gold junctions involving a well-defined metal carbonyl cluster compound.
2009
E., Leary; H., VAN ZALINGE; S., Higgins; R. J., Nichols; F., FABRIZI DE BIANI; Leoni, Piero; Marchetti, Lorella; P., Zanello
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11568/134586
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