The regioselectivity and stereoselectivity were examined of the addition reactions of O-, C-, N- and S-nucleophiles to D-allal-and D-galactal-derived N-mesylaziridines. The ratio of 1,4-regioselectivity (exclusive syn-1,4-addition) to 1,2-regioselectivity (exclusive anti-1,2-addition) was strictly and directly dependent on the aziridines.
D-allal and D-galactal-derived vinyl N-mesylaziridines: regio- and streoselectivity in addition reactions of O-, C-, N- and S-nucleopbiles
DI BUSSOLO, VALERIA;PINESCHI, MAURO;CROTTI, PAOLO
2012-01-01
Abstract
The regioselectivity and stereoselectivity were examined of the addition reactions of O-, C-, N- and S-nucleophiles to D-allal-and D-galactal-derived N-mesylaziridines. The ratio of 1,4-regioselectivity (exclusive syn-1,4-addition) to 1,2-regioselectivity (exclusive anti-1,2-addition) was strictly and directly dependent on the aziridines.File in questo prodotto:
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