The ambient temperature reaction of [Ir(η5-C5Me5)(CO)2] with Hg(CF3CO2)2 yields a mixed-metal cluster of iridium and mercury (see picture) which contains the novel Ir6Hg6 twelve-membered ring comprising six [Ir(η5-C5Me5)(CO)] fragments connected to each other through mercury centers; additional mercury centers and metal-metal bonds give rise to a network within the ring.
[{Ir(h5-C5Me5)(CO)}6Hg8][CF3CO2]6, a Mixed-Metal Cluster with an Ir6Hg6 Twelve-Membered Ring and Additional Hg Centers and Metal-Metal Bonds
INGROSSO, GIOVANNI;MARCHETTI, FABIO
2000-01-01
Abstract
The ambient temperature reaction of [Ir(η5-C5Me5)(CO)2] with Hg(CF3CO2)2 yields a mixed-metal cluster of iridium and mercury (see picture) which contains the novel Ir6Hg6 twelve-membered ring comprising six [Ir(η5-C5Me5)(CO)] fragments connected to each other through mercury centers; additional mercury centers and metal-metal bonds give rise to a network within the ring.File in questo prodotto:
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