A simple efficient, stereoselective, and highly regioselective method for the synthesis of beta-hydroxy sulfides by the direct opening of 1,2-epoxides with thiols in anhydrous acetonitrile, in the presence of a metal salt, is described. This new method appears to be competitive with the other methods previously reported.
STEREOSELECTIVE AND REGIOSELECTIVE METAL SALT-PROMOTED RING-OPENING OF 1,2-EPOXIDES WITH THIOLS IN ACETONITRILE
CROTTI, PAOLO;PINESCHI, MAURO
1992-01-01
Abstract
A simple efficient, stereoselective, and highly regioselective method for the synthesis of beta-hydroxy sulfides by the direct opening of 1,2-epoxides with thiols in anhydrous acetonitrile, in the presence of a metal salt, is described. This new method appears to be competitive with the other methods previously reported.File in questo prodotto:
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