The liquid phase methanol carbonylation to methyl formate has been investigated both with homogeneous sodium methoxide, the industrial catalyst for this process, and with heterogeneous strongly basic resins. The strongly basic resins Amberlyst A26 and Amberlite IRA 400 displayed a higher activity than sodium methoxide. The activation procedure and the dependence of the reaction rate on CO pressure have also been investigated.
Methanol carbonylation to methyl formate catalyzed by strongly basic resins
RASPOLLI GALLETTI, ANNA MARIA;SBRANA, GLAUCO
1996-01-01
Abstract
The liquid phase methanol carbonylation to methyl formate has been investigated both with homogeneous sodium methoxide, the industrial catalyst for this process, and with heterogeneous strongly basic resins. The strongly basic resins Amberlyst A26 and Amberlite IRA 400 displayed a higher activity than sodium methoxide. The activation procedure and the dependence of the reaction rate on CO pressure have also been investigated.File in questo prodotto:
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