The reductive coupling of the bridging phosphide and the adjacent sigma-alkynyl moieties in [Pt-2(mu-(PBu2)-Bu-t){mu,eta(1):eta(2)-C( Ph) CH2}(C=C - Ph)(CO)(P-t Bu2H)(Br)] is promoted by bromide abstraction and is reversed by adding (NBu4Br)-Bu-n.
Unprecedented Reversible Coupling of Alkynyl and Phosphide Ligands on a Dinuclear Platinum Framework
LEONI, PIERO;MARCHETTI, LORELLA;PASQUALI, MARCO;
2005-01-01
Abstract
The reductive coupling of the bridging phosphide and the adjacent sigma-alkynyl moieties in [Pt-2(mu-(PBu2)-Bu-t){mu,eta(1):eta(2)-C( Ph) CH2}(C=C - Ph)(CO)(P-t Bu2H)(Br)] is promoted by bromide abstraction and is reversed by adding (NBu4Br)-Bu-n.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
