EnglishThe previously observed regiocontrol of the ring-opening of epoxides bearing a remote polar group such as the title compounds (1 and 2) can also be achieved by metal-assisted methods for the direct aminolysis and azidolysis of epoxides. The appropriate use of the metal-assisted chelating or nonchelating procedures in the ring-opening of cis-epoxide 1 effects practically complete regiocontrol of these reactions, thus leading to regioalternating processes for the aminolysis and the azidolysis of 1.
| Autori: | |
| Autori: | CHINI M; CROTTI P; FLIPPIN LA; MACCHIA F |
| Titolo: | REGIOCHEMICAL CONTROL OF THE RING-OPENING OF 1,2-EPOXIDES BY MEANS OF CHELATING PROCESSES .3. AMINOLYSIS AND AZIDOLYSIS OF THE CIS-OXIDES AND TRANS-OXIDES DERIVED FROM 4-(BENZYLOXY)CYCLOHEXENE |
| Anno del prodotto: | 1991 |
| Digital Object Identifier (DOI): | 10.1021/jo00025a018 |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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