Coating materials characterised by intrinsic inhomogeneity or nanostructured morphology can display unique interfacial (e.g. surface and adhesion) and bulk (e.g. mechanical, thermal) properties, when heterophasic or self-segregating components are obtained by suitable design of the constitutive copolymers' structure. With the purpose of obtaining intrinsically photostable low-surface energy coating materials characterised by good penetration into porous substrates and variable response of the adhesive and polymer-air interface, fluorinated acrylic-based copolymers and water-borne acrylic-organosilane hybrids have been considered. For the latter, dispersed phase polymerisation procedures based on combined emulsion copolymerisation and hydrolysis-polycondensation of organosilane precursors have been adopted.
|Autori:||CASTELVETRO V.; MANARITI A.; DE VITA C.; CIARDELLI F|
|Titolo:||Synthesis and Surface Properties of Microphase Separated or Nanostructured Coatings Based on Hybrid and Fluorinated Acrylic Copolymers|
|Anno del prodotto:||2002|
|Digital Object Identifier (DOI):||10.1002/1521-3900(200209)187:1<165::AID-MASY165>3.0.CO;2-D|
|Appare nelle tipologie:||1.1 Articolo in rivista|