We present a model to evaluate the radiative and nonradiative lifetimes of electronic excited states of a molecule close to a metal particle of complex shape and, possibly, in the presence of a solvent. The molecule is treated quantum mechanically at Hartree–Fock HF or density-functional theory DFT level. The metal/solvent is considered as a continuous body, characterized by its frequency dependent local dielectric constant. For simple metal shapes planar infinite surface and spherical particle a version of the polarizable continuum model based on the integral equation formalism has been used, while an alternative methodology has been implemented to treat metal particles of arbitrary shape. In both cases, equations have been numerically solved using a boundary element method. Excitation energies and nonradiative decay rates due to the energy transfer from the molecule to the metal are evaluated exploiting the linear response theory TDHF or TDDFT where TD—time dependent. The radiative decay rate of the whole system moleculemetal/solvent is calculated, still using a continuum model, in terms of the response of the surrounding to the molecular transition. The model presented has been applied to the study of the radiative and nonradiative lifetimes of a lissamine molecule in solution water and close to gold spherical nanoparticles of different radius. In addition, the influence of the metal shape has been analyzed by performing calculations on a system composed by a coumarin-type molecule close to silver aggregates of complex shape.
|Autori:||ANDREUSSI O.; CORNI S.; MENNUCCI B.; TOMASI J|
|Titolo:||Radiative and nonradiative decay rates of a molecule close to a metal particle of complex shape|
|Anno del prodotto:||2004|
|Digital Object Identifier (DOI):||10.1063/1.1806819|
|Appare nelle tipologie:||1.1 Articolo in rivista|