A detailed description of the band system of the NO molecule has been achieved by calculating electronic transition moments, Einstein coefficients, and radiative lifetimes. The known strong interaction of the B2Π valence state with Rydberg states of 2Π symmetry is treated through a vibronic interaction matrix. This actually implies an extension of the molecular quantum defect orbital (MQDO) methodology in the study of vibronic levels of diatomic molecules.
|Autori:||E. BUSTOS; G. GRANUCCI; PERSICO M; A. M. VELASCO; I. MARTIN; C. LAVIN|
|Titolo:||A Theoretical Study for the Valence-Rydberg Interaction in Diatomic Molecules. Application to the NO beta Band System|
|Anno del prodotto:||2004|
|Digital Object Identifier (DOI):||10.1021/jp046924g|
|Appare nelle tipologie:||1.1 Articolo in rivista|