A new and efficient highly stereoselective method to prepare naturally-occurring 7-(hetero)aryl (2E,4E,6E)-2,4,6-heptatrienamides and their structural analogues has been developed. The physical and spectral properties of one of these compounds, i.e. (2E,4E,6E)-7-(2-thienyl)-2,4,6-heptatrienoic acid piperidide (4 b), have been found to be quite different from those previously reported for 7-(2-thienyl)-2,4,6-heptatrienoic acid piperidide isolated from Othantus maritimus to which the (2E,4E,6E)-configuration had been previously assigned.

Stereoselective synthesis of naturally-occurring 7-(hetero)aryl(2E,4E,6E)-2,4,6-heptatrienamides and their structural analogs

ROSSI, RENZO;CARPITA, ADRIANO;
1991

Abstract

A new and efficient highly stereoselective method to prepare naturally-occurring 7-(hetero)aryl (2E,4E,6E)-2,4,6-heptatrienamides and their structural analogues has been developed. The physical and spectral properties of one of these compounds, i.e. (2E,4E,6E)-7-(2-thienyl)-2,4,6-heptatrienoic acid piperidide (4 b), have been found to be quite different from those previously reported for 7-(2-thienyl)-2,4,6-heptatrienoic acid piperidide isolated from Othantus maritimus to which the (2E,4E,6E)-configuration had been previously assigned.
Rossi, Renzo; Carpita, Adriano; Lippolis, V.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11568/18901
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