Hemilabile phosphines by methyl acrylate insertion into the P-H bonds of palladium(I)-coordinated secondary phosphines. Labile anion (X = OTf) vs PO-chelate coordination (X = BF4) in Pd2(mu-PR2)(PR2R ')2(X) (R = Bu-t, R ' = CH2CH2COOMe; X = OTf, BF4)