β-D-Threo- and 4-deoxy-4-amino-α-D-erythro-hex-2-enopyranosyl di- (n=0) and trisaccharides (n=1) of types A and B were synthetized by means of a reiterative, completely stereoselective glycosylation process which makes use of the D-galactal-derived allyl epoxide 1β and D-allal-derived allyl N-Nosyl aziridine 2α, respectively.
Stereoselective Synthesis of 2,3-Unsaturated 1,6-Oligosaccharides by Means of a Glycal-derived Allyl Epoxide and N-Nosyl Aziridine
DI BUSSOLO, VALERIA;PINESCHI, MAURO;CROTTI, PAOLO
2008-01-01
Abstract
β-D-Threo- and 4-deoxy-4-amino-α-D-erythro-hex-2-enopyranosyl di- (n=0) and trisaccharides (n=1) of types A and B were synthetized by means of a reiterative, completely stereoselective glycosylation process which makes use of the D-galactal-derived allyl epoxide 1β and D-allal-derived allyl N-Nosyl aziridine 2α, respectively.File in questo prodotto:
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