Using the deoxycholic acid derived tropos biphenylphosphite 1 as Rh(I) chiral ligand different complexes are obtained, depending on the Rh:L molar ratio, that give rise to the formation of different chiral products in the asymmetric addition of phenylboronic acid to cyclohexenone.
Tunable coordination of a tropos phosphite for fine-tuning of the Rh catalyzed asymmetric addition of phenylboronic acid to cyclohexenone
IULIANO, ANNA;FUNAIOLI, TIZIANA
2009-01-01
Abstract
Using the deoxycholic acid derived tropos biphenylphosphite 1 as Rh(I) chiral ligand different complexes are obtained, depending on the Rh:L molar ratio, that give rise to the formation of different chiral products in the asymmetric addition of phenylboronic acid to cyclohexenone.File in questo prodotto:
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