The reaction of Pd(PtBu3)2 with the strong acids H3O+ X-, (X = BF3OH, BF4), gives the thermally unstable hydrides trans-[(tBu3P)2Pd(H)(H2O)]X. The thermally stable hydrides trans-[(tBu3P)2Pd(H) (CH,CN)]X were obtained by substitution of the water molecule by CH3CN. The reaction of the aquo-hydrides with CO, yielding [Pd(CO)(PtBu3)]2 and the crystal structure of trans[[(tBu3P)2Pd(H)(CH3CN)]BPh4 are also reported.
The reactivity of Pd(PtBu3)2 towards the oxonium ion. Crystal structure of trans-[(tBu3P)2 Pd(H)(CH3CN)]BPh4
PASQUALI, MARCO;LEONI, PIERO;
1991-01-01
Abstract
The reaction of Pd(PtBu3)2 with the strong acids H3O+ X-, (X = BF3OH, BF4), gives the thermally unstable hydrides trans-[(tBu3P)2Pd(H)(H2O)]X. The thermally stable hydrides trans-[(tBu3P)2Pd(H) (CH,CN)]X were obtained by substitution of the water molecule by CH3CN. The reaction of the aquo-hydrides with CO, yielding [Pd(CO)(PtBu3)]2 and the crystal structure of trans[[(tBu3P)2Pd(H)(CH3CN)]BPh4 are also reported.File in questo prodotto:
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