True new stable dinuclear Pd(I) complexes, [Pd-2(mu-PBu(t)2),(PPh(3))(3)]X and [Pd-2(mu-PBu(2)(t))(PPh(3))(2)(mu,eta(2): eta(2)-CS2)]X(X = BF4, CF3SO3), have been synthesized and characterized. The former has one 14e Pd center, and the latter, which has been characterized by X-ray diffraction, contains a CS2 molecule with a four-coordinate planar CS2 carbon.
A Stable Palladium(I) Dimer with One 14e- Palladium Center and its Reversible Reaction with CS2, Affording a New Complex with a Planar Four-Coordinate Carbon
LEONI, PIERO;PASQUALI, MARCO;
1995-01-01
Abstract
True new stable dinuclear Pd(I) complexes, [Pd-2(mu-PBu(t)2),(PPh(3))(3)]X and [Pd-2(mu-PBu(2)(t))(PPh(3))(2)(mu,eta(2): eta(2)-CS2)]X(X = BF4, CF3SO3), have been synthesized and characterized. The former has one 14e Pd center, and the latter, which has been characterized by X-ray diffraction, contains a CS2 molecule with a four-coordinate planar CS2 carbon.File in questo prodotto:
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