The structural features of a highly efficient hydrosilylation catalyst generated by reaction of Pt vapor and a mixture of mesitylene and 1,3-divinyltetramethyldisiloxane (DVS) were investigated by mono- and bidimensional NMR analyses. The structure around the Pt atoms was highlighted and compared with a commercial sample (Karstedt catalyst) and previously reported Pt vapor-derived system.

A New Platinum Vapour-Derived Highly Efficient Hydrosilylation Catalyst: NMR Structural Investigation

UCCELLO BARRETTA, GLORIA;BALZANO, FEDERICA;MANDOLI, ALESSANDRO;
2008

Abstract

The structural features of a highly efficient hydrosilylation catalyst generated by reaction of Pt vapor and a mixture of mesitylene and 1,3-divinyltetramethyldisiloxane (DVS) were investigated by mono- and bidimensional NMR analyses. The structure around the Pt atoms was highlighted and compared with a commercial sample (Karstedt catalyst) and previously reported Pt vapor-derived system.
UCCELLO BARRETTA, Gloria; Balzano, Federica; Evangelisti, C.; Raffa, P.; Mandoli, Alessandro; Nazzi, S.; Vitulli, G.
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11568/199007
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 10
  • ???jsp.display-item.citation.isi??? 10
social impact