The thermally unstable (decomp. ca. -30 degrees C) titanium derivative [TiCl4(SOCL2)](2), prepared from TiCl4 and SOCl2, forms three crystalline modifications (I-III) in temperature range between 220 and 234 K; these modifications differ in the orientation of the SOCl2 ligand with respect to the titanium-containing fragment within the dinuclear molecule and and in the packing modes due to intermolecular S ... Cl interactions at distances between 3.25 and 3.82 Angstrom.
Autori interni: | |
Autori: | CALDERAZZO F.; D'ATTOMA M.; MARCHETTI F.; PAMPALONI G; TROYANOV S.I. |
Titolo: | Labile Adducts of TiCl4 with Thionyl Chloride Structurally Characterized at Low Temperature: a Comparison with the Zirconium and Hafnium Analogues, [MCl4(SOCl2)]2, |
Anno del prodotto: | 1999 |
Digital Object Identifier (DOI): | 10.1039/a904186i |
Appare nelle tipologie: | 1.1 Articolo in rivista |
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