The thermally unstable (decomp. ca. -30 degrees C) titanium derivative [TiCl4(SOCL2)](2), prepared from TiCl4 and SOCl2, forms three crystalline modifications (I-III) in temperature range between 220 and 234 K; these modifications differ in the orientation of the SOCl2 ligand with respect to the titanium-containing fragment within the dinuclear molecule and and in the packing modes due to intermolecular S ... Cl interactions at distances between 3.25 and 3.82 Angstrom.
Labile Adducts of TiCl4 with Thionyl Chloride Structurally Characterized at Low Temperature: a Comparison with the Zirconium and Hafnium Analogues, [MCl4(SOCl2)]2,
CALDERAZZO, FAUSTO;MARCHETTI, FABIO;PAMPALONI, GUIDO;
1999
Abstract
The thermally unstable (decomp. ca. -30 degrees C) titanium derivative [TiCl4(SOCL2)](2), prepared from TiCl4 and SOCl2, forms three crystalline modifications (I-III) in temperature range between 220 and 234 K; these modifications differ in the orientation of the SOCl2 ligand with respect to the titanium-containing fragment within the dinuclear molecule and and in the packing modes due to intermolecular S ... Cl interactions at distances between 3.25 and 3.82 Angstrom.File in questo prodotto:
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