Enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid and its alkali metal salts performed in a chiral ionic liquid gave chiral cyclodimers in good enantiomeric excesses of up to 41%, which is the highest ever reported for a photochirogenic reaction in chiral media.

Photochirogenesis in chiral ionic liquid: enantiodifferentiating 4+4 photocyclodimerization of 2-anthracenecarboxylic acid in (R)-1-methyl-3-(2,3-dihydroxypropyl)imidazolium bistriflimide

CHIAPPE, CINZIA;BELLINA, FABIO;
2010

Abstract

Enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid and its alkali metal salts performed in a chiral ionic liquid gave chiral cyclodimers in good enantiomeric excesses of up to 41%, which is the highest ever reported for a photochirogenic reaction in chiral media.
Fukuhara, G; Chiappe, Cinzia; Mele, A; Melai, B; Bellina, Fabio; Inoue, Y.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11568/200074
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