Pd(OAc)(2) undergoes easy and quantitative coordination to a cross-linked styrene/divinylbenzene resin functionalized with bis(diphenylphosphino)methane ligands to yield a supported palladium complex which behaves as a versatile and recyclable heterogenized catalyst for the hydrogenation of nitrocompounds and alpha,beta-unsaturated aldehydes under mild conditions. Whereas nitrobenzene is converted only into aniline, cinnamaldehyde is selectively converted into hydrocin-namaldehyde. (C) 1999 Elsevier Science B.V. All rights reserved.

Hydrogenation of organic substrates by an heterogenized catalyst based on a bis(diphenylphosphine)methane polymer-bound palladium(II) complex

CARLINI, CARLO;RASPOLLI GALLETTI, ANNA MARIA;SBRANA, GLAUCO
1999

Abstract

Pd(OAc)(2) undergoes easy and quantitative coordination to a cross-linked styrene/divinylbenzene resin functionalized with bis(diphenylphosphino)methane ligands to yield a supported palladium complex which behaves as a versatile and recyclable heterogenized catalyst for the hydrogenation of nitrocompounds and alpha,beta-unsaturated aldehydes under mild conditions. Whereas nitrobenzene is converted only into aniline, cinnamaldehyde is selectively converted into hydrocin-namaldehyde. (C) 1999 Elsevier Science B.V. All rights reserved.
F., Benvenuti; Carlini, Carlo; M., Marchionna; RASPOLLI GALLETTI, ANNA MARIA; Sbrana, Glauco
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11568/200117
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