1-O-Hexadecyl and 1,2-di-O-hexadecyl-3-O-(beta-D-glucopyranosyl)-sn-glycerol ethers were obtained by regiospecific opening of the oxirane ring of the 2',3'-epoxypropyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-glucopyranoside synthetized by stereoselective epoxidation of the corresponding allyl 3,4,6-tri-O-benzyl-beta-D-glucopyranoside asymmetrically induced by the glucide moiety. (C) 1997 Published by Elsevier Science Ltd.
|Autori:||Bellucci G; Catelani G; Chiappe C; DAndrea F; Grigo G|
|Titolo:||An efficient stereoselective synthesis of enantiomerically pure mono- and di-O-hexadecyl-beta-D-glucosylglycerol ethers by epoxidation of an allyl-beta-D-glucopyranoside asymmetrically induced by the glucide moiety|
|Anno del prodotto:||1997|
|Digital Object Identifier (DOI):||10.1016/S0957-4166(97)00041-4|
|Appare nelle tipologie:||1.1 Articolo in rivista|