The bis-ethylene derivative [Pt(μ-PBut 2)(η2-CH2LCH2)]2 was prepared and characterized by X-ray diffraction; its protonation affords [Pt2(μ-PBut 2)(μ-PBut 2H)(η2-CH2LCH2)2]-(CF3SO3), with a rarely observed P–H–M agostic proton in rapid exchange with those of the adjacent ethylene molecule.
Structure and Protonation of the Bis-Ethylene Adduct [Pt(mu-PBut2)(eta2-CH2=CH2)]2. Pt-H-P Agostic Interaction and Proton Scrambling
LEONI, PIERO;MARCHETTI, FABIO;MARCHETTI, LORELLA;
2004
Abstract
The bis-ethylene derivative [Pt(μ-PBut 2)(η2-CH2LCH2)]2 was prepared and characterized by X-ray diffraction; its protonation affords [Pt2(μ-PBut 2)(μ-PBut 2H)(η2-CH2LCH2)2]-(CF3SO3), with a rarely observed P–H–M agostic proton in rapid exchange with those of the adjacent ethylene molecule.File in questo prodotto:
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