A simple, efficient, stereoselective, and regioselective method for the synthesis of beta-alkoxy alcohols by the direct opening of 1,2-epoxides with alcohols (primary, secondary, and tertiary) in a nonprotic solvent or with the alcohol itself as the solvent, in the presence of a metal salt, is described. This new method appears to be competitive with and/or alternative to the other methods previously reported.
METAL SALT-PROMOTED ALCOHOLYSIS OF 1,2-EPOXIDES
CROTTI, PAOLO;
1992-01-01
Abstract
A simple, efficient, stereoselective, and regioselective method for the synthesis of beta-alkoxy alcohols by the direct opening of 1,2-epoxides with alcohols (primary, secondary, and tertiary) in a nonprotic solvent or with the alcohol itself as the solvent, in the presence of a metal salt, is described. This new method appears to be competitive with and/or alternative to the other methods previously reported.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
